| Anabel Medina Garrigues - A Jidkova | 6-4 6-1 |
| Mary Pierce - Shuai Peng | 6-1 7-5 |
| S Mamic - Daniela Hantuchova (16) | 6-1 6-2 |
| . Bovina (9) - M Washington | 6-2 6-2 |
| Roberta Vinci - . Chladkova | 7-6 6-1 |
| P Suarez - K Sprem | 6-3 6-0 |
| Gisela Dulko - V Ruano Pascual | 6-3 7-5 |
| . Linetskaya - Tathiana Garbin | 6-3 6-4 |
| Flavia Pennetta - S Asagoe (14) | 6-2 6-3 |
| Ana Ivanovic - Tatiana Golovin (12) | 6-3 6-4 |
| Anna Chakvetadze - L Kurhajcova | 6-3 3-6 6-1 |
| Anna-Lena Groenefeld - Antonella Serra-Zanetti | 6-1 6-2 |
| Jelena Jankovic - D Randriantefy | 6-7 6-2 6-1 |
| Catalina Castano - T Perebiynis | 6-3 6-2 |
| Maria Elena Camerin - Nathalie Dechy (10) | 4-6 6-1 6-4 |
| Ai Sugiyama (15) - . Maleeva Mag | 6-2 6-4 |
| M Vento - Virginie Razzano | 6-4 7-6 |
| Francesca Schiavone - Meghann Shaughnessy | 7-5 6-0 |
| Mara Santangelo - Zuluaga | 6-2 6-2 |
| Conchita Martinez - A Haynes | 6-0 6-1 |
| Anna Smashnova - Elena Likhovtseva (11) | 6-1 6-3 |
| . Farina (13) - Maria Kirilenko | 6-4 6-1 |
| S Cohen Aloro - N Vierin | 2-6 7-6 6-2 |
| Samantha Stosur - Y Fedak | 6-3 6-3 |
| Maria Sharapova (1) - Anabel Medina Garrigues | 6-4 6-2 |
| Mary Pierce - S Mamic | 6-4 6-4 |
| . Bovina (9) - Roberta Vinci | 7-5 6-2 |
| P Suarez - Svetlana Kuznetsova (5) | 6-2 6-4 |
| Gisela Dulko - Elena Dementieva (4) | 7-5 6-4 |
| . Linetskaya - Flavia Pennetta | 6-2 4-6 7-6 |
| Ana Ivanovic - Anna Chakvetadze | 5-7 6-3 6-2 |
| Patty Schnyder (8) - Anna-Lena Groenefeld | 6-2 6-4 |
| Vera Zvonareva (6) - Jelena Jankovic | 6-4 6-1 |
| Catalina Castano - Maria Elena Camerin | 6-2 6-2 |
| Ai Sugiyama (15) - M Vento | 6-3 6-0 |
| Francesca Schiavone - Serena Williams (3) | 7-6 6-1 |
| Nadja Petrova (7) - Mara Santangelo | 6-3 6-1 |
| Conchita Martinez - Anna Smashnova | 3-6 6-1 6-1 |
| . Farina (13) - S Cohen Aloro | 6-3 6-3 |
| Amelie Mauresmo (2) - Samantha Stosur | 6-2 6-0 |