| Gilles Simon - Filippo Volandri | 6-2 6-3 |
| Andrey Golubev - Fernando Verdasco | 6-4 7-5 |
| Mikhail Youzhny (14) - Nicolas Mahut | 6-4 6-4 |
| Jurgen Melzer - John Isner (9) | 7-6 6-3 |
| Marin Cilic - Santiago Giraldo | 6-4 2-0 rit |
| Marcel Granollers - Feliciano Lopez | 7-5 6-1 |
| Pere Riba - Paolo Lorenzi | 7-6 6-3 |
| Igor Sijsling - Marco Cecchinato | 7-6 7-5 |
| Tommy Haas (15) - Andreas Seppi | 6-1 4-6 6-4 |
| Grigor Dimitrov (12) - Christophe Roger Vaseelin | 4-6 6-3 6-4 |
| Ivo Karlovic - Pablo Carreno Busta | 3-6 6-3 7-6 |
| Dmitry Tursunov - Roberto Bautista Agut | 6-0 7-6 |
| Simone Bolelli - Stefano Travaglia | 3-6 7-5 7-6 |
| Kevin Anderson - Vasek Pospisil | 7-5 7-6 |
| Jo Wilfred Tsonga (11) - Alexandr Dolgopolov | 6-3 7-6 |
| VasekLukas Rosol - Fabio Fognini (13) | 6-3 6-2 |
| Ivan Dodig - Federico Delbonis | 6-3 6-4 |
| Jeremy Chardy - Robin Haase | 6-4 6-4 |
| Mikhail Kukushkin - Joao Sousa | 6-3 6-7 6-3 |
| Stephane Robert - Alejandro Gonzalez | 1-6 6-4 6-1 |
| Ernest Gulbis - Alejandro Falla | 6-1 rit |
| Tommy Robredo (16) - Juan Monaco | 7-6 6-4 |
| Philipp Kohlschreiber - Jerzy Janowicz | 4-6 7-6 6-2 |
| Radek Stepanek - Pablo Andujar | 5-7 6-3 6-4 |
| Rafael Nadal (1) - Gilles Simon | 7-6 6-7 6-2 |
| Mikhail Youzhny (14) - Andrey Golubev | 7-5 4-1 rit |
| Jurgen Melzer - Marin Cilic | 6-2 6-7 6-3 |
| Andy Murray (7) - Marcel Granollers | 6-2 7-5 |
| Stanislas Wawrinka (3) - Pere Riba | 6-0 6-3 |
| Tommy Haas (15) - Igor Sijsling | 7-6 6-1 |
| Grigor Dimitrov (12) - Ivo Karlovic | 7-6 6-4 |
| Tomas Berdych (6) - Dmitry Tursunov | 6-4 6-3 |
| Milos Raonic (8) - Simone Bolelli | 6-3 7-6 |
| Jo Wilfred Tsonga (11) - Kevin Anderson | 7-6 7-6 |
| Ivan Dodig - VasekLukas Rosol | 6-1 6-2 |
| Jeremy Chardy - Roger Federer (4) | 1-6 6-3 7-6 |
| David Ferrer (5) - Mikhail Kukushkin | 6-1 6-2 |
| Ernest Gulbis - Stephane Robert | 6-7 6-4 6-3 |
| Philipp Kohlschreiber - Tommy Robredo (16) | 6-2 6-4 |
| Novak Djokovic (2) - Radek Stepanek | 6-3 7-5 |