| Albert Montanes - Martin Klizan | 3-6 7-5 6-3 |
| Alexandr Dolgopolov - Matteo Viola | 6-4 6-3 |
| Stanislas Wawrinka (15) - Carlos Berlocq | 5-7 6-3 6-3 |
| Marin Cilic (11) - Andrey Golubev | 6-4 6-2 |
| Kevin Anderson - Jurgen Melzer | 6-1 6-2 |
| Denis Istomin - John Isner | 5-7 7-6 6-3 |
| Fernando Verdasco - Horacio Zeballos | 6-3 3-6 6-3 |
| Albert Ramos Viñolas - Jan Hajek | 7-5 6-0 |
| Philipp Kohlschreiber - Milos Raonic (14) | 7-6 6-4 |
| Victor Troicki - VasekLukas Rosol | 3-6 6-1 6-4 |
| Ernest Gulbis - Jarkko Nieminen | 6-2 7-6 |
| Fabio Fognini - Andreas Seppi | 6-4 6-1 |
| Andrey Kuznetsov - Xavier Malisse | 6-2 3-1 rit |
| Benoit Paire - Juan Monaco | 7-6 1-6 6-4 |
| Julien Benneteau - Nicolas Almagro (12) | 7-6 6-4 |
| Kei Nishikori (16) - Paolo Lorenzi | 6-2 6-4 |
| Jeremy Chardy - Feliciano Lopez | 3-6 7-5 7-6 |
| Marcel Granollers - Nikolay Davydenko | 6-3 6-4 |
| Jerzy Janowicz - Santiago Giraldo | 7-5 6-2 |
| Grigor Dimitrov - Marcos Baghdatis | 6-3 6-4 |
| Richard Gasquet (9) - Sam Querrey | 6-2 7-6 |
| Mikhail Youzhny - Tommy Haas (13) | 6-4 6-3 |
| Gilles Simon - Filippo Volandri | 6-3 2-6 6-4 |
| Potito Starace - Radek Stepanek | 4-6 6-4 6-3 |
| Novak Djokovic (1) - Albert Montanes | 6-2 6-3 |
| Alexandr Dolgopolov - Stanislas Wawrinka (15) | rin |
| Kevin Anderson - Marin Cilic (11) | 6-3 7-6 |
| Tomas Berdych (6) - Denis Istomin | 6-4 6-0 |
| David Ferrer (4) - Fernando Verdasco | 5-7 7-5 6-3 |
| Philipp Kohlschreiber - Albert Ramos Viñolas | 6-4 6-1 |
| Ernest Gulbis - Victor Troicki | 6-1 6-1 |
| Rafael Nadal (5) - Fabio Fognini | 6-1 6-3 |
| Juan Martin Del Potro (7) - Andrey Kuznetsov | 6-3 6-2 |
| Benoit Paire - Julien Benneteau | 6-7 6-4 7-6 |
| Jeremy Chardy - Kei Nishikori (16) | 6-4 6-1 |
| Marcel Granollers - Andy Murray (3) | 6-3 6-7 rit |
| Jerzy Janowicz - Jo Wilfred Tsonga (8) | 6-4 7-6 |
| Richard Gasquet (9) - Grigor Dimitrov | 6-4 6-4 |
| Gilles Simon - Mikhail Youzhny | 7-5 6-3 |
| Roger Federer (2) - Potito Starace | 6-1 6-2 |