| Ernest Gulbis - Marcos Baghdatis | 6-2 6-2 |
| Filippo Volandri - P Luczak | 6-4 6-3 |
| Julien Benneteau - Sam Querrey (15) | 7-6 3-6 7-6 |
| Ivan Ljubicic (11) - Paul Henri Mathieu | 7-5 6-7 6-0 |
| Nicolas Almagro - Lukasz Kubot | 6-7 6-2 6-3 |
| Feliciano Lopez - Benjamin Becker | 6-4 6-3 |
| Philipp Kohlschreiber - Pablo Cuevas | 6-7 6-1 6-4 |
| Victor Hanescu - M Berrer | 6-2 6-7 6-3 |
| Juan Monaco (16) - Igor Andreev | 7-6 7-5 |
| Tomas Berdych (10) - Marcel Granollers | 6-3 6-3 |
| Stanislas Wawrinka - Jurgen Melzer | 6-1 6-2 |
| Paolo Lorenzi - Albert Montanes | 2-6 6-4 6-3 |
| Victor Troicki - Thiemo De Bakker | 3-6 6-1 1-0 rit |
| Michael Llodra - A Beck | 6-2 3-6 6-4 |
| Santiago Giraldo - Juan Carlos Ferrero (12) | 6-0 6-3 |
| David Ferrer (13) - Evgeny Korolev | 6-4 6-1 |
| Potito Starace - Jan Hernych | 6-2 6-2 |
| Andreas Seppi - Fabio Fognini | 6-0 6-3 |
| Simone Bolelli - S Greul | 6-4 6-1 |
| Guillermo Garcia Lopez - Juan Ignacio Chela | 6-2 6-2 |
| Lleyton Hewitt - Mikhail Youzhny (9) | 6-4 4-6 6-3 |
| John Isner (14) - Horacio Zeballos | 4-6 7-6 7-5 |
| Thomaz Bellucci - Leonardo Mayer | 6-4 3-6 6-1 |
| Jeremy Chardy - Janko Tipsarevic | 6-4 6-4 |
| Ernest Gulbis - Roger Federer (1) | 2-6 6-1 7-5 |
| Filippo Volandri - Julien Benneteau | 6-2 6-0 |
| Ivan Ljubicic (11) - Nicolas Almagro | 7-5 7-6 |
| Feliciano Lopez - Marin Cilic (8) | 2-6 7-6 6-4 |
| Rafael Nadal (3) - Philipp Kohlschreiber | 6-1 6-3 |
| Victor Hanescu - Juan Monaco (16) | 7-6 6-4 |
| Stanislas Wawrinka - Tomas Berdych (10) | 2-6 6-3 7-6 |
| Robin Soderling (5) - Paolo Lorenzi | 6-1 7-5 |
| Jo Wilfred Tsonga (7) - Victor Troicki | 6-2 6-3 |
| Santiago Giraldo - Michael Llodra | 6-3 6-2 |
| David Ferrer (13) - Potito Starace | 7-5 6-2 |
| Andy Murray (4) - Andreas Seppi | 6-2 6-4 |
| Fernando Verdasco (6) - Simone Bolelli | 7-6 6-3 |
| Guillermo Garcia Lopez - Lleyton Hewitt | 7-6 7-5 |
| Thomaz Bellucci - John Isner (14) | 7-6 7-5 |
| Novak Djokovic (2) - Jeremy Chardy | 6-1 6-1 |