| Andreas Seppi - Sam Querrey | 3-6 6-4 6-3 |
| Robin Soderling - Marcel Granollers | 6-3 6-0 |
| V Crivoi - James Blake (14) | 7-5 6-3 |
| Richard Gasquet - Jo Wilfred Tsonga (9) | 7-6 6-4 |
| Ernest Gulbis - Nicolas Almagro | 3-6 7-6 6-2 |
| Mardy Fish - Igor Andreev | 6-3 4-6 7-6 |
| Juan Monaco - Nicolas Kiefer | 6-2 6-3 |
| Christophe Rochus - Juan Ignacio Chela | 6-1 6-2 |
| Marin Cilic (15) - Flavio Cipolla | 6-2 6-2 |
| Fernando Gonzalez (12) - Jeremy Chardy | 6-4 6-1 |
| Janko Tipsarevic - Jose Acasuso | 6-3 6-4 |
| Jurgen Melzer - Julien Benneteau | 3-6 6-2 6-3 |
| Victor Troicki - Victor Hanescu | 6-3 6-3 |
| Mikhail Youzhny - D Gimeno | 7-5 6-4 |
| Stanislas Wawrinka (10) - Igor Kunitsyn | 6-3 6-4 |
| Tommy Robredo (13) - Marat Safin | 2-6 7-6 6-2 |
| Philipp Kohlschreiber - Simone Bolelli | 4-6 6-1 6-0 |
| Albert Montanes - Potito Starace | 7-6 6-4 |
| Fabio Fognini - Filippo Volandri | 6-7 6-1 7-6 |
| Alexander Zverev - Tomas Berdych | 4-6 6-2 7-5 |
| Paul Henri Mathieu - David Ferrer (11) | 6-3 2-6 6-2 |
| Radek Stepanek (16) - Florent Serra | 7-6 4-6 7-5 |
| Feliciano Lopez - Thomaz Bellucci | 6-4 6-2 |
| Ivo Karlovic - Jan Hernych | 4-6 6-4 6-2 |
| Rafael Nadal (1) - Andreas Seppi | 6-2 6-3 |
| Robin Soderling - V Crivoi | 6-1 6-7 6-1 |
| Richard Gasquet - Ernest Gulbis | 6-2 1-6 6-4 |
| Fernando Verdasco (6) - Mardy Fish | 6-4 5-7 6-3 |
| Juan Monaco - Andy Murray (4) | 1-6 6-3 7-5 |
| Marin Cilic (15) - Christophe Rochus | 6-0 5-7 6-2 |
| Fernando Gonzalez (12) - Janko Tipsarevic | 6-4 6-4 |
| Jurgen Melzer - Nikolay Davydenko (7) | 7-5 7-6 |
| Juan Martin Del Potro (5) - Victor Troicki | 6-3 1-6 6-3 |
| Stanislas Wawrinka (10) - Mikhail Youzhny | 6-3 7-6 |
| Tommy Robredo (13) - Philipp Kohlschreiber | 6-2 7-6 |
| Novak Djokovic (3) - Albert Montanes | 7-6 6-0 |
| Gilles Simon (8) - Fabio Fognini | 6-7 6-2 6-3 |
| Alexander Zverev - Paul Henri Mathieu | 3-6 7-6 6-0 |
| Radek Stepanek (16) - Feliciano Lopez | 6-2 6-1 |
| Roger Federer (2) - Ivo Karlovic | 6-4 6-4 |