| Nicolas Almagro - Tim Henman | 7-5 6-1 |
| Filippo Volandri - Teimuraz Gabashvili | 6-0 6-3 |
| Richard Gasquet (13) - Fernando Verdasco | 6-1 7-5 |
| Tomas Berdych (12) - Jarkko Nieminen | 6-4 7-5 |
| Albert Montanes - Stanislas Wawrinka | 3-6 6-1 7-6 |
| Jose Acasuso - Martin Verkerk | 6-3 7-5 |
| Gaston Gaudio - Mardy Fish | 6-4 6-4 |
| Juan Ignacio Chela - Marc Gicquel | 2-6 6-4 6-1 |
| Igor Andreev - David Ferrer (14) | 6-4 6-1 |
| James Blake (9) - Gael Monfils | 7-6 6-3 |
| Nicolas Massu - Simone Bolelli | 6-3 7-6 |
| Dmitry Tursunov - Jonas Bjorkman | 7-6 3-6 6-1 |
| Oscar Hernandez - Lleyton Hewitt | 3-6 7-6 6-1 |
| Guillermo Canas - Jurgen Melzer | 7-5 6-2 |
| Gilles Simon - Andy Murray (10) | 6-1 1-6 6-3 |
| Juan Carlos Ferrero (16) - Dominik Hrbaty | 3-6 6-1 6-4 |
| Potito Starace - Agustin Calleri | 6-3 6-1 |
| Marat Safin - Amer Delic | 2-6 6-3 6-4 |
| Robin Soderling - Benjamin Becker | 6-3 6-3 |
| Marcos Baghdatis - Carlos Moya | 6-2 6-3 |
| Radek Stepanek - Tommy Haas (11) | 6-3 3-2 rit. |
| Mikhail Youzhny (15) - Julien Benneteau | 6-1 3-6 6-2 |
| Olivier Rochus - Michael Llodra | 5-7 6-3 6-3 |
| Daniele Bracciali - Robby Ginepri | 7-5 7-6 |
| Roger Federer (1) - Nicolas Almagro | 6-3 6-4 |
| Filippo Volandri - Richard Gasquet (13) | 6-4 6-7 6-4 |
| Tomas Berdych (12) - Albert Montanes | 7-6 6-3 |
| Jose Acasuso - Ivan Ljubicic (8) | 6-4 6-3 |
| Andy Roddick (3) - Gaston Gaudio | 6-1 7-6 |
| Juan Ignacio Chela - Igor Andreev | 7-5 7-5 |
| Nicolas Massu - James Blake (9) | 7-6 7-5 |
| Fernando Gonzalez (6) - Dmitry Tursunov | 6-2 6-1 |
| Tommy Robredo (7) - Oscar Hernandez | 7-5 4-6 6-1 |
| Gilles Simon - Guillermo Canas | 7-6 6-4 |
| Potito Starace - Juan Carlos Ferrero (16) | 6-2 3-6 6-2 |
| Nikolay Davydenko (4) - Marat Safin | 7-6 7-5 |
| Novak Djokovic (5) - Robin Soderling | 3-6 6-4 6-3 |
| Marcos Baghdatis - Radek Stepanek | 3-6 7-6 6-2 |
| Mikhail Youzhny (15) - Olivier Rochus | 7-6 6-3 |
| Rafael Nadal (2) - Daniele Bracciali | 6-2 6-2 |