| Roger Federer (1) - Juan Ignacio Chela | 6-2 6-1 |
| Potito Starace - Dmitry Tursunov | 6-4 6-1 |
| Jarkko Nieminen - Sebastien Grosjean | 6-2 6-1 |
| Radek Stepanek (14) - Feliciano Lopez | 6-4 6-4 |
| Jose Acasuso - David Ferrer (11) | 7-5 6-0 |
| Nicolas Almagro - Nicolas Massu | 7-5 6-4 |
| Fernando Verdasco - Simone Bolelli | 6-4 2-6 6-1 |
| Nikolay Davydenko (6) - B Pashanski | 6-1 6-4 |
| David Nalbandian (4) - Fernando Vicente | 6-2 3-6 6-3 |
| Paul Henri Mathieu - Juan Carlos Ferrero | 6-1 6-3 |
| Alberto Martin - Davide Sanguinetti | 6-4 6-2 |
| Nicolas Kiefer (13) - Daniele Bracciali | 4-6 6-2 6-4 |
| Hidalgo Ruben Ramirez - Guillermo Coria (9) | 6-3 6-2 |
| Marat Safin - Teimuraz Gabashvili | 7-5 3-6 6-1 |
| Mario Ancic - Luis Horna | 6-4 6-4 |
| Florent Serra - James Blake (7) | 6-4 7-6 |
| Andy Roddick (5) - Victor Hanescu | 6-1 6-0 |
| Marcos Baghdatis - Olivier Rochus | 7-5 6-4 |
| Stefano Galvani - Jiri Novak | 6-3 6-4 |
| Greg Rusedski - Tommy Robredo (12) | 5-7 6-3 6-4 |
| Robby Ginepri (16) - Max Mirnyi | 3-6 6-2 6-3 |
| Gael Monfils - Tommy Haas | 6-2 3-6 6-4 |
| Fabrice Santoro - Juan Monaco | 4-6 6-2 6-3 |
| Dominik Hrbaty - Ivan Ljubicic (3) | 5-7 7-6 6-4 |
| Xavier Malisse - Gaston Gaudio (8) | 4-6 6-3 6-3 |
| Tomas Berdych - Paradorn Srichaphan | 6-1 6-3 |
| Mikhail Youzhny - Andreas Seppi | 6-2 7-6 |
| Fernando Gonzalez (10) - Stanislas Wawrinka | 6-4 6-4 |
| Thomas Johansson (15) - Fabio Fognini | 7-6 6-3 |
| Tim Henman - Alessio Di Mauro | 7-5 7-6 |
| Filippo Volandri - Andy Murray | 6-4 6-4 |
| Rafael Nadal (2) - Carlos Moya | 6-1 2-6 6-2 |
| Roger Federer (1) - Potito Starace | 6-3 7-6 |
| Radek Stepanek (14) - Jarkko Nieminen | 6-4 7-6 |
| Nicolas Almagro - Jose Acasuso | 6-4 2-6 6-4 |
| Nikolay Davydenko (6) - Fernando Verdasco | 6-1 3-6 6-0 |
| David Nalbandian (4) - Paul Henri Mathieu | 6-2 6-4 |
| Alberto Martin - Nicolas Kiefer (13) | 6-3 7-6 |
| Hidalgo Ruben Ramirez - Marat Safin | 0-6 7-6 7-6 |
| Mario Ancic - Florent Serra | 3-6 7-6 6-0 |
| Andy Roddick (5) - Marcos Baghdatis | 3-6 6-1 6-2 |
| Greg Rusedski - Stefano Galvani | 7-6 6-4 |
| Gael Monfils - Robby Ginepri (16) | 6-1 4-6 6-4 |
| Fabrice Santoro - Dominik Hrbaty | 7-6 6-3 |
| Tomas Berdych - Xavier Malisse | 6-2 6-1 |
| Fernando Gonzalez (10) - Mikhail Youzhny | 6-4 5-7 6-3 |
| Tim Henman - Thomas Johansson (15) | 7-6 6-1 |
| Rafael Nadal (2) - Filippo Volandri | 6-1 6-2 |