| Andy Roddick (1) - Greg Rusedski | 6-4 6-2 |
| Albert Costa - Albert Montanes | 6-4 6-4 |
| Stanislas Wawrinka - Tomas Berdych | 6-1 6-4 |
| Fernando Verdasco - Nikolay Davydenko (14) | 6-3 7-5 |
| Guillermo Coria (9) - Fernando Gonzalez | 7-6 5-7 6-4 |
| Nicolas Kiefer - Tommy Haas | 6-3 6-1 |
| Davide Sanguinetti - Max Mirnyi | 5-7 6-4 7-6 |
| Fabrice Santoro - David Nalbandian (8) | 6-4 1-6 6-4 |
| Tim Henman (4) - Gustavo Kuerten | 6-3 6-3 |
| Nicolas Massu - Paul Henri Mathieu | 6-0 6-4 |
| Nicolas Massu - R Mello | 6-4 6-3 |
| Julien Benneteau - Tommy Robredo (13) | 6-1 6-0 |
| Ivan Ljubicic (12) - Olivier Rochus | 6-3 6-3 |
| Sebastien Grosjean - Kenneth Carlsen | 6-3 6-2 |
| Richard Gasquet - Paradorn Srichaphan | 6-0 6-2 |
| Andre Agassi (6) - Alessio Di Mauro | 7-5 6-2 |
| Potito Starace - Carlos Moya (7) | 6-4 7-6 |
| Alberto Martin - Rainer Schuettler | 6-0 1-0 |
| Luis Horna - Florian Mayer | 4-6 6-3 7-5 |
| Andreas Seppi - Joachim Johansson (10) | 6-1 6-2 |
| Thomas Johansson (16) - Feliciano Lopez | 6-3 6-2 |
| David Ferrer - Cyril Saulnier | 6-1 6-3 |
| Filippo Volandri - Younes El Aynaoui | 6-0 6-2 |
| Gaston Gaudio (3) - Karol Beck | 6-4 6-3 |
| Rafael Nadal (5) - Mikhail Youzhny | 6-0 6-2 |
| Victor Hanescu - Jurgen Melzer | 6-4 3-6 6-3 |
| Juan Monaco - Robin Soderling | 6-3 6-2 |
| Guillermo Canas (11) - Andrei Pavel | 7-5 6-2 |
| Radek Stepanek (15) - Mario Ancic | 6-1 6-7 6-3 |
| Juan Ignacio Chela - Michael Llodra | 6-4 6-4 |
| Nicolas Almagro - Igor Andreev | 3-6 6-4 6-1 |
| Marat Safin (2) - Jiri Novak | 6-7 6-1 6-1 |
| Andy Roddick (1) - Albert Costa | 6-4 7-5 |
| Fernando Verdasco - Stanislas Wawrinka | 7-6 6-2 |
| Guillermo Coria (9) - Nicolas Kiefer | 6-1 6-1 |
| Davide Sanguinetti - Fabrice Santoro | 6-3 7-5 |
| Tim Henman (4) - Nicolas Massu | 6-3 6-2 |
| Dominik Hrbaty - Julien Benneteau | 7-6 6-0 |
| Ivan Ljubicic (12) - Sebastien Grosjean | 6-4 3-6 6-3 |
| Andre Agassi (6) - Richard Gasquet | 6-2 6-3 |
| Alberto Martin - Potito Starace | 6-3 3-6 6-3 |
| Luis Horna - Andreas Seppi | 2-6 6-3 6-4 |
| David Ferrer - Thomas Johansson (16) | 6-3 6-4 6-4 |
| Gaston Gaudio (3) - Filippo Volandri | 6-4 6-2 |
| Rafael Nadal (5) - Victor Hanescu | 6-1 6-1 |
| Guillermo Canas (11) - Juan Monaco | 6-0 6-0 |
| Radek Stepanek (15) - Juan Ignacio Chela | 6-4 4-6 6-1 |
| Nicolas Almagro - Marat Safin (2) | 6-4 6-3 |