| David Ferrer - Andre Agassi (1) | 0-6 7-6 6-4 |
| Ivan Ljubicic - Xavier Malisse | 6-2 6-4 |
| Victor Hanescu - Mikhail Youzhny | 7-6 6-3 |
| Guillermo Coria (15) - Tim Henman | 6-2 6-1 |
| Felix Mantilla - David Nalbandian (11) | 6-3 1-6 6-0 |
| Mardy Fish - Fabrice Santoro | 7-5 7-5 |
| Arnaud Clement - Davide Sanguinetti | 6-1 6-3 |
| Albert Costa (7) - F Krajan | 6-4 7-5 |
| Carlos Moya (3) - Fernando Vicente | 6-2 6-4 |
| Max Mirnyi - Nicolas Lapentti | 4-6 7-6 6-3 |
| Giorgio Galimberti - Brian Vahaly | 7-5 4-6 6-3 |
| Yevgeny Kafelnikov - Younes El Aynaoui (16) | 6-1 1-6 6-4 |
| Jarkko Nieminen - Paradorn Srichaphan (9) | 6-1 6-2 |
| Nikolay Davydenko - Karol Kucera | 2-6 6-1 7-5 |
| Martin Verkerk - Vincent Spadea | 6-3 7-6 |
| Andy Roddick (5) - Andrea Gaudenzi | 6-2 6-3 |
| Filippo Volandri - Nicolas Massu | 1-6 6-2 6-1 |
| Raemon Sluiter - Jan Michael Gambill | 6-4 4-6 6-2 |
| Radek Stepanek - James Blake | 6-2 1-6 6-3 |
| Alberto Martin - Sjeng Schalken (10) | 2-6 6-3 6-1 |
| Tommy Robredo - Sebastien Grosjean (13) | 6-7 6-4 6-3 |
| Juan Ignacio Chela - Olivier Rochus | 6-1 6-1 |
| Mariano Zabaleta - David Sanchez | 6-4 6-2 |
| Roger Federer (4) - Paul Henri Mathieu | 6-3 7-5 |
| Jiri Novak (8) - Wayne Arthurs | 6-3 6-3 |
| Dominik Hrbaty - Thomas Enqvist | 6-3 6-3 |
| Wayne Ferreira - Feliciano Lopez | 3-6 6-4 6-3 |
| Rainer Schuettler (12) - Magnus Norman | 7-6 7-5 |
| Gaston Gaudio - Gustavo Kuerten (14) | 6-3 2-6 6-4 |
| Agustin Calleri - Stefan Koubek | 6-2 6-2 |
| Alex Corretja - A Portas | 3-6 6-2 6-2 |
| Juan Carlos Ferrero (2) - Mark Philippoussis | 7-6 6-4 |
| Ivan Ljubicic - David Ferrer | 6-2 6-3 |
| Guillermo Coria (15) - Victor Hanescu | 6-1 7-6 |
| Felix Mantilla - Mardy Fish | 6-4 6-3 |
| Albert Costa (7) - Arnaud Clement | 6-7 6-2 6-4 |
| Carlos Moya (3) - Max Mirnyi | 6-4 6-4 |
| Yevgeny Kafelnikov - Giorgio Galimberti | 7-5 6-2 |
| Jarkko Nieminen - Nikolay Davydenko | 7-5 4-6 6-1 |
| Martin Verkerk - Andy Roddick (5) | 6-7 6-3 6-4 |
| Filippo Volandri - Raemon Sluiter | 6-1 7-5 |
| Radek Stepanek - Alberto Martin | 6-4 6-3 |
| Tommy Robredo - Juan Ignacio Chela | 6-2 6-0 |
| Roger Federer (4) - Mariano Zabaleta | 7-6 6-2 |
| Jiri Novak (8) - Dominik Hrbaty | 6-1 6-4 |
| Rainer Schuettler (12) - Wayne Ferreira | 7-6 6-2 |
| Gaston Gaudio - Agustin Calleri | 6-4 6-2 |
| Juan Carlos Ferrero (2) - Alex Corretja | 6-4 6-4 |